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Showing posts with label salts. Show all posts
Showing posts with label salts. Show all posts

Wednesday, 30 September 2015

Liquid water flows on today's Mars: NASA confirms evidence

New findings from NASA's Mars Reconnaissance Orbiter (MRO) provide the strongest evidence yet that liquid water flows intermittently on present-day Mars.

Using an imaging spectrometer on MRO, researchers detected signatures of hydrated minerals on slopes where mysterious streaks are seen on the Red Planet. These darkish streaks appear to ebb and flow over time. They darken and appear to flow down steep slopes during warm seasons, and then fade in cooler seasons. They appear in several locations on Mars when temperatures are above minus 10 degrees Fahrenheit (minus 23 Celsius), and disappear at colder times.

Martian slopes. Credit: NASA/JPL-Caltech/Univ. of Arizona

"Our quest on Mars has been to 'follow the water,' in our search for life in the universe, and now we have convincing science that validates what we've long suspected," said John Grunsfeld, astronaut and associate administrator of NASA's Science Mission Directorate in Washington. "This is a significant development, as it appears to confirm that water -- albeit briny -- is flowing today on the surface of Mars."

These downhill flows, known as recurring slope lineae (RSL), often have been described as possibly related to liquid water. The new findings of hydrated salts on the slopes point to what that relationship may be to these dark features. The hydrated salts would lower the freezing point of a liquid brine, just as salt on roads here on Earth causes ice and snow to melt more rapidly. Scientists say it's likely a shallow subsurface flow, with enough water wicking to the surface to explain the darkening.

"We found the hydrated salts only when the seasonal features were widest, which suggests that either the dark streaks themselves or a process that forms them is the source of the hydration. In either case, the detection of hydrated salts on these slopes means that water plays a vital role in the formation of these streaks," said Lujendra Ojha of the Georgia Institute of Technology (Georgia Tech) in Atlanta, lead author of a report on these findings published Sept. 28 by Nature Geoscience.

Ojha first noticed these puzzling features as a University of Arizona undergraduate student in 2010, using images from the MRO's High Resolution Imaging Science Experiment (HiRISE). HiRISE observations now have documented RSL at dozens of sites on Mars. The new study pairs HiRISE observations with mineral mapping by MRO's Compact Reconnaissance Imaging Spectrometer for Mars (CRISM).

The spectrometer observations show signatures of hydrated salts at multiple RSL locations, but only when the dark features were relatively wide. When the researchers looked at the same locations and RSL weren't as extensive, they detected no hydrated salt.

Ojha and his co-authors interpret the spectral signatures as caused by hydrated minerals called perchlorates. The hydrated salts most consistent with the chemical signatures are likely a mixture of magnesium perchlorate, magnesium chlorate and sodium perchlorate. Some perchlorates have been shown to keep liquids from freezing even when conditions are as cold as minus 94 degrees Fahrenheit (minus 70 Celsius). On Earth, naturally produced perchlorates are concentrated in deserts, and some types of perchlorates can be used as rocket propellant.

Perchlorates have previously been seen on Mars. NASA's Phoenix lander and Curiosity rover both found them in the planet's soil, and some scientists believe that the Viking missions in the 1970s measured signatures of these salts. However, this study of RSL detected perchlorates, now in hydrated form, in different areas than those explored by the landers. This also is the first time perchlorates have been identified from orbit.

MRO has been examining Mars since 2006 with its six science instruments.
"The ability of MRO to observe for multiple Mars years with a payload able to see the fine detail of these features has enabled findings such as these: first identifying the puzzling seasonal streaks and now making a big step towards explaining what they are," said Rich Zurek, MRO project scientist at NASA's Jet Propulsion Laboratory in Pasadena, California.

For Ojha, the new findings are more proof that the mysterious lines he first saw darkening Martian slopes five years ago are, indeed, present-day water.

"When most people talk about water on Mars, they're usually talking about ancient water or frozen water," he said. "Now we know there's more to the story. This is the first spectral detection that unambiguously supports our liquid water-formation hypotheses for RSL."

The discovery is the latest of many breakthroughs by NASA's Mars missions.

"It took multiple spacecraft over several years to solve this mystery, and now we know there is liquid water on the surface of this cold, desert planet," said Michael Meyer, lead scientist for NASA's Mars Exploration Program at the agency's headquarters in Washington. "It seems that the more we study Mars, the more we learn how life could be supported and where there are resources to support life in the future."

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Friday, 3 April 2015

Stained and Coloured Glass

Stained glass can refer to coloured glass as a material or to works created from it - most commonly seen in the stained glass windows of churches and other buildings.  Coloured glass is also found in everyday life such as green wine bottles.



As a material stained glass is glass that has been coloured by adding metallic salts during its manufacture.

There are two main types of glass - soda lime glass - commonly used in beverage bottles and the like and borosilicate glass - used in laboratory glassware and also some domestic glassware such as oven proof dishes.

Coloured glass is made in a number of ways.  There are three main ways.

The first involves introducing metallic or rare earth metal oxides to the glass as mentioned above.

Silver compounds for example such as silver nitrate are used as stain applied to the surface of glass and fired on. They can produce a range of colours from orange-red to yellow. The way the glass is heated and cooled can significantly affect the colours produced by these compounds.

Another way is by formation of colloidal particles. This means particles of a substance are suspended throughout the glass. The particles scatter light of particular frequencies as it passes through the glass, causing colouration.

Gold gives a ruby red colour, and selenium gives a pink to intense red.

The final main way in which colour can be introduced is through the addition of already coloured particles to the glass. Examples of this type of colouration include milk glass and smoked glass; milk glass is achieved by adding tin oxide.

The infographic below from Compound Interest shows what chemicals are involved in the colour process.  Click for a larger image.


Click to enlarge
For more information visit:-
http://en.wikipedia.org/wiki/Stained_glass
http://www.compoundchem.com/2015/03/03/coloured-glass/

Friday, 5 September 2014

Back to school

Where did the summertime break go?  Time for kids to go back to school.  And time for us too...chemistry basics.....Acids and bases

All acids:
  • have a low pH (1-6) – the lower the number the stronger the acid
  • react with bases to form neutral compounds
  • are corrosive when they are strong
  • are an irritant when they are weak.
Acids have a pH of less than 7. Bases have a pH of more than 7. When bases are dissolved in water, they are known as alkalis. Salts are made when an acid reacts with a base, carbonate or metal. The name of the salt formed depends on the metal in the base and the acid used. For example, salts made using hydrochloric acid are called chlorides.


Acids
Substances with a pH of less than 7 are acids. The more strongly acidic the solution, the lower its pH number. Acidic solutions turn blue litmus paper red. They turn universal indicator paper red if they are strongly acidic, and orange or yellow if they are weakly acidic.

Bases
Substances that can react with acids and neutralise them to make a salt and water are called bases. They are usually metal oxides or metal hydroxides. For example, copper oxide and sodium hydroxide are bases.

Alkalis
Bases that dissolve in water are called alkalis. Copper oxide is not an alkali because it does not dissolve in water. Sodium hydroxide is an alkali because it does dissolve in water.

Alkaline solutions have a pH of more than 7. The stronger the alkali, the higher the pH number. Alkalis turn red litmus paper blue. They turn universal indicator paper dark blue or purple if they are strongly alkaline, and blue-green if they are weakly alkaline.

Neutral solutions
Neutral solutions have a pH of 7. They do not change the colour of litmus paper, but they turn universal indicator paper green. Water is neutral.

For pH meters or pH test papers or buffer solutions give us a call.

For more information visit:-
http://www.prlabs.co.uk
http://en.wikipedia.org/wiki/PH