Total Lab Supplies - Everything for your laboratory

Total Lab Supplies - Everything for your laboratory
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Friday, 27 June 2014

Potassium Hydroxide.

Potassium hydroxide is an inorganic compound with the formula KOH, commonly called caustic potash.

Potassium Hydroxide is noteworthy as the precursor to most soft and liquid soaps as well as numerous potassium-containing chemicals.

Potassium hydroxide can be found in pure form by reacting sodium hydroxide with impure potassium. Potassium hydroxide is usually sold as white or translucent pellets, sometimes yellow, which will become tacky in air because KOH is hygroscopic. Consequently, KOH typically contains varying amounts of water (as well as carbonates).

Its dissolution in water is strongly exothermic, meaning the process gives off significant heat. Concentrated aqueous solutions are sometimes called potassium lyes. Even at high temperatures, solid KOH does not dehydrate readily.

Potassium hydroxide has many uses:-
  • Precursor to other potassium compounds, eg fertilisers
  • Manufacture of biodiesel
  • Manufacture of soft soaps
  • As an electrolyte
  • Cleaning and disinfection
  • As a main active ingredient in chemical "cuticle removers" used in manicure treatments
Health information
  • Potassium Hydroxide is highly corrosive and contact can severely irritate and burn the skin and eyes leading to damage
  • Potassium Hydroxide can affect you when inhaled and by passing through the skin
  • Contact can irritate the nose and throat
  • Inhaling can irritate the lungs causing a build up of fluid
  • Exposure can cause headaches, dizziness, nausea and vomiting
  • It may cause skin allergy.

All health and safety data information must be followed when using this chemical

Friday, 20 June 2014

Ultrasonic Baths

An ultrasonic cleaner is a cleaning device that uses ultrasound (usually from 20–400 kHz) and an appropriate cleaning solvent (sometimes ordinary tap water) to clean delicate items. The ultrasound can be used with just water, but use of a solvent appropriate for the item to be cleaned and the soiling enhances the effect. Cleaning normally lasts between three and six minutes, but can also exceed 20 minutes, depending on the object to be cleaned.

Ultrasonic cleaning penetrates even microscopic openings to provide complete cleaning of the objects treated. This makes it one of the most effective, economical and powerful cleaning methods available. It has applications in laboratories, dental and medical technology, microelectronics, precision engineering, cosmetics, optics and the automotive industry. Ultrasonic cleaners are used to clean many different types of objects, including jewellery, lenses and other optical parts, watches, dental and surgical instruments, tools, coins, fountain pens, golf clubs, window blinds, firearms, musical instruments, industrial parts and electronic equipment. They are used in many jewellery workshops, watchmakers' establishments, and electronic repair workshops               
Modern baths tend to have a heavy duty ultrasonic generator which ensures that the ultrasonic output remains constant, regardless of the bath temperature, fill level and cleaning material. This feature guarantees consistent and reproducible cleaning results. 'Frequency sweeping', a frequency modulation of the ultrasonic output generated, prevents 'standing waves' from being generated and ensures extremely homogeneous energy distribution in the cleaning bath.
 
Ultrasonic cleaning uses Cavitation bubbles induced by high frequency pressure (sound) waves to agitate a liquid. The agitation produces high forces on contaminants adhering to substrates like metals, plastics, glass, rubber, and ceramics. This action also penetrates blind holes, cracks, and recesses. The intention is to thoroughly remove all traces of contamination tightly adhering or embedded onto solid surfaces. Water or other solvents can be used, depending on the type of contamination and the workpiece.
 
There are various ways to test the level of ultrasonic activity within an ultrasonic bath..
 
There are a number of recommended tests for establishing levels of ultrasonic activity in the bath.

The foil test involves suspending a strip of foil into various locations around the tank. The foil should not touch the base of the tank and should be held in position for around 1 minute. It should then be removed and there should be an even distribution of perforations and small holes on the surface of the foil.

Another test requires the use of Brownes soil test strips. These are plastic strips which have been contaminated to simulate the contamination which might affect surgical instruments. After running an ultrasonic cycle the strips should be taken from the bath and all contamination should have been removed.

An ultrasonic energy meter can also be used to test the level of ultrasonic activity within the tank.

For more information on ultrasonic baths visit:-
http://www.prlabs.co.uk/lab-supplies.php?N=ULTRASONIC-BATH-1L-MECH.-TIMER%26HEATER&Id=64514
http://en.wikipedia.org/wiki/Ultrasonic_bath

Friday, 13 June 2014

Pyroclastic flows

Pyroclastic flows are high-density mixtures of hot, dry rock fragments and hot gases that move away from the vent that erupted them at high speeds. They may result from the explosive eruption of molten or solid rock fragments, or both. They may also result from the nonexplosive eruption of lava when parts of dome or a thick lava flow collapses down a steep slope. Most pyroclastic flows consist of two parts: a basal flow of coarse fragments that moves along the ground, and a turbulent cloud of ash that rises above the basal flow. Ash may fall from this cloud over a wide area downwind from the pyroclastic flow.


Pyroclastic flows can reach speeds moving away from a volcano of up to 700 km/h (450 mph).  The gas can reach temperatures of about 1,000 °C (1,830 °F). Pyroclastic flows normally hug the ground and travel downhill, or spread laterally under gravity. Their speed depends upon the density of the current, the volcanic output rate, and the gradient of the slope. They are a common and devastating result of certain explosive volcanic eruptions.

A pyroclastic flow will destroy nearly everything in its path. With rock fragments ranging in size from ash to boulders traveling across the ground at speeds typically greater than 80 km per hour, pyroclastic flows knock down, shatter, bury or carry away nearly all objects and structures in their way. The extreme temperatures of rocks and gas inside pyroclastic flows can cause combustible material to burn, especially petroleum products, wood, vegetation, and houses.

Testimonial evidence from the 1883 eruption of Krakatoa, supported by experimental evidence, shows that pyroclastic flows can cross significant bodies of water. One flow reached the Sumatran coast as much as 48 km away.

Pyroclastic flows sweep down the flanks of Mayon Volcano, Philippines, in 1984

The towns of Pompeii and Herculaneum, Italy, for example, were engulfed by pyroclastic surges in 79 AD with many lives lost.

"Garden of the Fugitives". Plaster casts of victims still in situ; many casts are in the Archaeological Museum of Naples.
For more information and some video clips visit:-
http://www.geo.mtu.edu/volcanoes/hazards/primer/pyro.html
http://en.wikipedia.org/wiki/Pyroclastic_flow
http://volcanoes.usgs.gov/hazards/pyroclasticflow/

Friday, 6 June 2014

Antimony

Antimony is a chemical element with symbol Sb (from Latin: stibium) and atomic number 51. A lustrous grey metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3).
 

Antimony compounds have been known since ancient times and were used for cosmetics.  Nowadays Antimony is mainly used as its trioxide in making flame-proofing compounds and in certain alloys.  The Egyptians had a hieroglyph for Antimony......


Antimony has no known biological role, but it is a potent toxin, with effects that are similar to arsenic poisoning. When ingested, antimony strongly bonds to sulfur-containing enzymes, thereby inactivating them. Antimony is even more toxic when inhaled as the gas, stibine, SbH3. Poisoning by antimony ingestion manifests as gastric distress, and large doses cause vomiting, and kidney and liver damage, followed by death a few days later.

It was thought that Mozart was a victim of poisoning at the hand of rival composer, Antonio Salieri, although historians don't give this hypothesis any credence. It is far more likely that Mozart was poisoned by his doctors. A heavy drinker, Mozart was known to also overindulge in the popular hangover cure of the day that contains antimony, tartar emetic, C4H4KO7Sb, which was provided by his doctors.

Stibnite

For some time, China has been the largest producer of antimony and its compounds, with most production coming from the Xikuangshan Mine in Hunan. The industrial methods to produce antimony are roasting and subsequent carbothermal reduction or direct reduction of stibnite with iron.

For more information visit:-
http://www.theguardian.com/science/grrlscientist/2012/feb/24/1?guni=Article:in%20body%20link
http://en.wikipedia.org/wiki/Antimony





Friday, 30 May 2014

Three Nuclear Accidents - An infographic.

Following on from last weeks post the Infographic below details three major nuclear accidents and the outcomes.  Graphic courtesy of LiveScience.
chernobyl nuclear disaster infographic
Source:LiveScience

Friday, 23 May 2014

The Chernobyl Nuclear Plant Disaster

28 years ago in the early morning hours of April 26, 1986, the Chernobyl nuclear power plant in Ukraine (formerly part of the Soviet Union) exploded, creating what has been described as the worst nuclear disaster the world has ever seen.
 
Chernobyl is located about 81 miles (130 km) north of the city of Kiev in Ukraine, and about 12 miles (20 km) south of the border with Belarus.  The four reactors at the Chernobyl Nuclear Power Plant were designed and built during the 1970s and 1980s. A manmade reservoir, roughly 8.5 square miles (22 sq. km) in size and fed by the Pripyat River, was created to provide cooling water for the reactor.



On 26 April 1986, at 01:23, reactor four suffered a catastrophic power increase, leading to explosions in its core. This dispersed large quantities of radioactive fuel and core materials into the atmosphere and ignited the combustible graphite moderator. The burning graphite moderator increased the emission of radioactive particles, carried by the smoke, as the reactor had not been encased by any kind of hard containment vessel. The accident occurred during an experiment scheduled to test a potential safety emergency core cooling feature, which took place during a normal shutdown procedure.
In most nuclear reactors, where water is used as a coolant and to moderate the reactivity of the nuclear core, as the core heats up and produces more steam, the increase in steam bubbles or "voids" in the water reduces the reactivity in the nuclear core. This is an important safety feature found in most reactors built in the United States and other Western nations.
 
But not in the RBMK-1000, which used graphite to moderate the core's reactivity and to keep a continuous nuclear reaction occurring in the core. As the nuclear core heated and produced more steam bubbles, the core became more reactive, not less, creating a positive-feedback loop that engineers refer to as a "positive-void coefficient."
Basically, when extremely hot nuclear fuel rods were lowered into cooling water, an immense amount of steam was created, which — because of the RBMK reactors' design flaws — created more reactivity in the nuclear core of reactor number 4. The resultant power surge caused an immense explosion that detached the 1,000-ton plate covering the reactor core, releasing radiation into the atmosphere and cutting off the flow of coolant into the reactor.
A few seconds later, a second explosion of even greater power than the first blew the reactor building apart and spewed burning graphite and other parts of the reactor core around the plant, starting a number of intense fires around the damaged reactor and reactor number 3, which was still operating at the time of the explosions.
The explosions killed two plant workers, who were the first of several workers to die within hours of the accident. For the next several days, as emergency crews tried desperately to contain the fires and radiation leaks, the death toll climbed as plant workers succumbed to acute radiation sickness.
Most of the radiation released from the failed nuclear reactor was from iodine-131, cesium-134 and cesium-137. Iodine-131 has a relatively short half-life of eight days, according to UNSCEAR, but is rapidly ingested through the air and tends to localize in the thyroid gland. Cesium isotopes have longer half-lives (cesium-137 has a half-life of 30 years) and are a concern for years after their release into the environment. 

On April 27, the residents of Pripyat were evacuated — about 36 hours after the accident had occurred. By that time, many were already complaining about vomiting, headaches and other signs of radiation sickness. Officials eventually closed off an 18-mile (30 km) area around the plant; residents were told they would be able to return after a few days, so many left their personal belongings and valuables behind.

Abandoned Pripyat
During the construction of the sarcophagus, a scientific team re-entered the reactor as part of an investigation dubbed "Complex Expedition", to locate and contain nuclear fuel in a way that could not lead to another explosion. These scientists manually collected cold fuel rods, but great heat was still emanating from the core. Rates of radiation in different parts of the building were monitored by drilling holes into the reactor and inserting long metal detector tubes. The scientists were exposed to high levels of radiation and radioactive dust.

After six months of investigation, in December 1986, they discovered with the help of a remote camera an intensely radioactive mass in the basement of Unit Four, more than two metres wide and weighing hundreds of tons, which they called "the elephant's foot" for its wrinkled appearance. The mass was composed of sand, glass and a large amount of nuclear fuel that had escaped from the reactor. The concrete beneath the reactor was steaming hot, and was breached by solidified lava and spectacular unknown crystalline forms termed chernobylite. It was concluded that there was no further risk of explosion.

Contamination from the Chernobyl accident was scattered irregularly depending on weather conditions, much of it deposited on mountainous regions such as the Alps, the Welsh mountains and the Scottish Highlands, where adiabatic cooling caused radioactive rainfall.

For more information visit:-
http://en.wikipedia.org/wiki/Chernobyl_disaster
http://www.livescience.com/39961-chernobyl.html
 

Friday, 16 May 2014

Magnesium

Magnesium has the atomic number 12 and is an alkaline earth metal with the symbol Mg. It is a common element, the eighth-most-abundant element in the Earth's crust and ninth in the known universe as a whole. Magnesium is the fourth-most-common element in the Earth as a whole (behind iron, oxygen and silicon), making up 13% of the planet's mass and a large fraction of the planet's mantle.




The free element (metal) is not found naturally on Earth, as it is highly reactive (though once produced, it is coated in a thin layer of oxide (see passivation), which partly masks this reactivity). The free metal burns with a characteristic brilliant-white light, making it a useful ingredient in flares. You probably remember burning Magnesium Ribbon in school.  Some of the light that burning magnesium produces is in the ultraviolet range. Just as ultraviolet light will burn your skin, it will also burn the retinas of your eyes if they are not protected, hence not looking directly at the light or using suitable safety eyewear.



Since magnesium is less dense than aluminium, these alloys are prized for their relative lightness and strength.

Magnesium has many uses, but most of us are familiar with aluminium-magnesium alloys, which are often found in cell phones and other electronic gadgets that must be strong yet light weight. Gardeners and tropical fish hobbyists are also very familiar with magnesium, since plants need it to grow (a magnesium deficiency is indicated by yellow leaves).  Animals need small amounts of magnesium to support proper bodily functions too.

For more information visit:-
http://en.wikipedia.org/wiki/Magnesium
http://www.theguardian.com/science/punctuated-equilibrium/2011/may/13/1?guni=Article:in%20body%20link