On this day...

In 1980, following a weeklong series of earthquakes and smaller explosions of ash and smoke, the long-dormant Mount St. Helens volcano erupted in Washington state, U.S., hurling ash 15,000 feet into the air and setting off mudslides and avalanches.

18/05/1980

An earthquake at 8:32:17 a.m. on Sunday, May 18, 1980, caused the entire weakened north face to slide away, creating the largest landslide ever recorded. This allowed the partly molten, high-pressure gas- and steam-rich rock in the volcano to suddenly explode northwards toward Spirit Lake in a hot mix of lava and pulverized older rock.

Approximately 57 people were killed directly.  Hundreds of square miles were reduced to wasteland, causing over a billion U.S. dollars in damage, thousands of animals were killed, and Mount St. Helens was left with a crater on its north side.

Lakes nearest to Mount St. Helens have been partly covered with felled trees for more than thirty years. This photograph was taken in 2012.

For more information visit:-
https://en.wikipedia.org/wiki/1980_eruption_of_Mount_St._Helens

On this day in science history: Mars 5 launched

In 1973, the USSR launched Mars 5, on a Proton SL-12/D-1-e booster. It was one of several Soviet Mars probes - Mars 4, 5, 6, and 7 - launched in Jul-Aug 1973. The Mars 5 mission was to orbit Mars, which was achieved on 12 Feb 1974. Each orbit took about 25 hours. It was designed to return information on the composition, structure, and properties of the martian atmosphere and surface. However, after only 22 orbits, the mission ended prematurely due to loss of pressurization in the transmitter housing. Before the failure, data for a small portion of the martian southern hemisphere was captured with about 60 images forwarded over a nine day period. The probe also sent more measurements made by other instruments.

Mars in natural colour in 2007. By ESA - European Space Agency & Max-Planck Institute for Solar System Research for OSIRIS Team ESA/MPS/UPD/LAM/IAA/RSSD/INTA/UPM/DASP/IDA [CC BY-SA 3.0-igo (http://creativecommons.org/licenses/by-sa/3.0-igo)], via Wikimedia Commons

Mars is the fourth planet from the Sun and the second-smallest planet in the Solar System, after Mercury. Named after the Roman god of war, it is often referred to as the "Red Planet" because the iron oxide prevalent on its surface gives it a reddish appearance. Mars is a terrestrial planet with a thin atmosphere, having surface features reminiscent both of the impact craters of the Moon and the valleys, deserts, and polar ice caps of Earth.

The rotational period and seasonal cycles of Mars are likewise similar to those of Earth, as is the tilt that produces the seasons. Mars is the site of Olympus Mons, the largest volcano and second-highest known mountain in the Solar System, and of Valles Marineris, one of the largest canyons in the Solar System. The smooth Borealis basin in the northern hemisphere covers 40% of the planet and may be a giant impact feature. Mars has two moons, Phobos and Deimos, which are small and irregularly shaped. These may be captured asteroids, similar to 5261 Eureka, a Mars trojan.

There are ongoing investigations assessing the past habitability potential of Mars, as well as the possibility of extant life. Liquid water cannot exist on the surface of Mars due to low atmospheric pressure, which is less than 1% of the Earth's, except at the lowest elevations for short periods. The two polar ice caps appear to be made largely of water. The volume of water ice in the south polar ice cap, if melted, would be sufficient to cover the entire planetary surface to a depth of 11 meters (36 ft). In November 2016, NASA reported finding a large amount of underground ice in the Utopia Planitia region of Mars. 

The volume of water detected has been estimated to be equivalent to the volume of water in Lake Superior.

Mars can easily be seen from Earth with the naked eye, as can its reddish coloring. Its apparent magnitude reaches −2.91, which is surpassed only by Jupiter, Venus, the Moon, and the Sun. Optical ground-based telescopes are typically limited to resolving features about 300 kilometers (190 mi) across when Earth and Mars are closest because of Earth's atmosphere.

For more information, visit:-

https://todayinsci.com/7/7_25.htm

https://en.wikipedia.org/wiki/Mars

http://www.prlabs.co.uk/lab-supplies.php?N=iron-1000ppm-for-icp&Id=60139

On this day in science history: Mount Vesuvius erupted

In 79, the long-dormant Mount Vesuvius erupted in Italy, burying the Roman cities of Pompeii and Herculaneum in volcanic ash. An estimated 20,000 people died. When discovered, the sites became astonishing archaeological time capsules. Official excavations began on 6 Apr 1748 of behalf of the Italian king's interest in collecting antiquities.

Pompeii, with Vesuvius towering above. Qfl247 CC BY-SA 3.0 (http://creativecommons.org/licenses/by-sa/3.0) or GFDL (http://www.gnu.org/copyleft/fdl.html), via Wikimedia Commons

Scientific knowledge of the geologic history of Vesuvius comes from core samples taken from a 2,000 m (6,600 ft) plus bore hole on the flanks of the volcano, extending into Mesozoic rock. Cores were dated by potassium–argon and argon–argon dating. The mountain started forming 25,000 years ago. Although the area has been subject to volcanic activity for at least 400,000 years, the lowest layer of eruption material from the Somma mountain lies on top of the 40,000‑year‑old Campanian Ignimbrite produced by the Campi Flegrei complex, and was the product of the Codola Plinian eruption 25,000 years ago.

It was then built up by a series of lava flows, with some smaller explosive eruptions interspersed between them. However, the style of eruption changed around 19,000 years ago to a sequence of large explosive plinian eruptions, of which the 79 AD one was the most recent. The eruptions are named after the tephra deposits produced by them, which in turn are named after the location where the deposits were first identified:

• The Basal Pumice (Pomici di Base) eruption, 18,300 years ago, VEI 6, saw the original formation of the Somma caldera. The eruption was followed by a period of much less violent, lava producing eruptions.
• The Green Pumice (Pomici Verdoline) eruption, 16,000 years ago, VEI 5.
• The Mercato eruption (Pomici di Mercato) – also known as Pomici Gemelle or Pomici Ottaviano – 8000 years ago, VEI 6, followed a smaller explosive eruption around 11,000 years ago (called the Lagno Amendolare eruption).
• The Avellino eruption (Pomici di Avellino), 3800 years ago, VEI 5, followed two smaller explosive eruptions around 5,000 years ago. The Avellino eruption vent was apparently 2 km west of the current crater, and the eruption destroyed several Bronze Age settlements of the Apennine culture. Several carbon dates on wood and bone offer a range of possible dates of about 500 years in the mid-2nd millennium BC. In May 2001, near Nola, Italian archaeologists using the technique of filling every cavity with plaster or substitute compound recovered some remarkably well-preserved forms of perishable objects, such as fence rails, a bucket and especially in the vicinity thousands of human footprints pointing into the Apennines to the north. The settlement had huts, pots, and goats. The residents had hastily abandoned the village, leaving it to be buried under pumice and ash in much the same way that Pompeii was later preserved. Pyroclastic surge deposits were distributed to the northwest of the vent, travelling as far as 15 km (9.3 mi) from it, and lie up to 3 m (9.8 ft) deep in the area now occupied by Naples.

The volcano then entered a stage of more frequent, but less violent, eruptions until the most recent Plinian eruption, which destroyed Pompeii.

The last of these may have been in 217 BC. There were earthquakes in Italy during that year and the sun was reported as being dimmed by a haze or dry fog. Plutarch wrote of the sky being on fire near Naples and Silius Italicus mentioned in his epic poem Punica that Vesuvius had thundered and produced flames worthy of Mount Etna in that year, although both authors were writing around 250 years later. Greenland ice core samples of around that period show relatively high acidity, which is assumed to have been caused by atmospheric hydrogen sulfide.

The mountain was then quiet (for 295 years, if the 217 BC date for the last previous eruption is true) and was described by Roman writers as having been covered with gardens and vineyards, except at the top which was craggy. The mountain may have had only one summit at that time, judging by a wall painting, "Bacchus and Vesuvius", found in a Pompeiian house, the House of the Centenary (Casa del Centenario).

Several surviving works written over the 200 years preceding the 79 AD eruption describe the mountain as having had a volcanic nature, although Pliny the Elder did not depict the mountain in this way in his Naturalis Historia:

• The Greek historian Strabo (ca 63 BC–AD 24) described the mountain in Book V, Chapter 4 of his Geographica as having a predominantly flat, barren summit covered with sooty, ash-coloured rocks and suggested that it might once have had "craters of fire". He also perceptively suggested that the fertility of the surrounding slopes may be due to volcanic activity, as at Mount Etna.
• In Book II of De architectura, the architect Vitruvius reported that fires had once existed abundantly below the mountain and that it had spouted fire onto the surrounding fields. He went on to describe Pompeiian pumice as having been burnt from another species of stone.
• Diodorus Siculus (ca 90 BC–ca 30 BC), another Greek writer, wrote in Book IV of his Bibliotheca Historica that the Campanian plain was called fiery (Phlegrean) because of the mountain, Vesuvius, which had spouted flame like Etna and showed signs of the fire that had burnt in ancient history.

For more information visit:-

http://www.todayinsci.com/8/8_24.htm

https://en.wikipedia.org/wiki/Mount_Vesuvius

Diamonds may not be so rare as once thought

Diamonds may not be as rare as once believed, but this finding in a new Johns Hopkins University research report won't mean deep discounts at local jewellery stores.

"Diamond formation in the deep Earth, the very deep Earth, may be a more common process than we thought," said Johns Hopkins geochemist Dimitri A. Sverjensky, whose article co-written with doctoral student Fang Huang appears today in the online journal Nature Communications. The report says the results 'constitute a new quantitative theory of diamond formation,' but that does not mean it will be easier to find gem-quality diamonds and bring them to market.

"Rough diamond" by Unknown USGS employee - Original source: USGS "Minerals in Your World" website. 

For one thing, the prevalence of diamonds near the Earth's surface - where they can be mined - still depends on relatively rare volcanic magma eruptions that raise them from the depths where they form. For another, the diamonds being considered in these studies are not necessarily the stuff of engagement rings, unless the recipient is equipped with a microscope. Most are only a few microns across and are not visible to the unaided eye.

Using a chemical model, Sverjensky and Huang found that these precious stones could be born in a natural chemical reaction that is simpler than the two main processes that up to now have been understood to produce diamonds. Specifically, their model - yet to be tested with actual materials - shows that diamonds can form with an increase in acidity during interaction between water and rock.

The common understanding up to now has been that diamonds are formed in the movement of fluid by the oxidation of methane or the chemical reduction of carbon dioxide. Oxidation results in a higher oxidation state, or a gain of electrons. Reduction means a lower oxidation state, and collectively the two are known as 'redox' reactions.

"It was always hard to explain why the redox reactions took place," said Sverjensky, a professor in the Morton K. Blaustein Department of Earth and Planetary Sciences in the university's Krieger School of Arts and Sciences. The reactions require different types of fluids to be moving through the rocks encountering environments with different oxidation states.

The new research showed that water could produce diamonds as its pH falls naturally - that is, as it becomes more acidic - while moving from one type of rock to another, Sverjensky said.

The finding is one of many in about the last 25 years that expands scientists' understanding of how pervasive diamonds may be, Sverjensky said.

"The more people look, the more they're finding diamonds in different rock types now," Sverjensky said. "I think everybody would agree there's more and more environments of diamond formation being discovered."

Nobody has yet put a number on the greater abundance of diamonds, but Sverjensky said scientists are working on that with chemical models. It's impossible to physically explore the great depths at which diamonds are created: roughly 90 to 120 miles below the Earth's surface at intense pressure and at temperatures about 1,650 to 2,000 degrees Fahrenheit.

The deepest drilling exploration ever made was about 8 or 9 miles below the surface, he said.

If the study doesn't shake the diamond markets, it promises to help shed light on fluid movement in the deep Earth, which helps account for the carbon cycle on which all life on the planet depends.

"Fluids are the key link between the shallow and the deep Earth," Sverjensky said. "That's why it's important."

This research was supported by grants from the Sloan Foundation through the Deep Carbon Observatory (Reservoirs and Fluxes and Extreme Physics and Chemistry programs) and by a U.S. Energy Department grant, DE-FG-02-96ER-14616.

For more information visit:

http://www.sciencedaily.com/releases/2015/11/151103140444.htm

https://www.prlabs.co.uk/lab-supplies.php?N=bisdiphenylphosphino-methane-for-sy&Id=38134

Volcanic rocks resembling Roman concrete explain record uplift in Italian caldera

The discovery of a fiber-reinforced, concrete-like rock formed in the depths of a dormant supervolcano could help explain the unusual ground swelling that led to the evacuation of an Italian port city and inspire durable building materials in the future, Stanford scientists say.

The "natural concrete" at the Campi Flegrei volcano is similar to Roman concrete, a legendary compound invented by the Romans and used to construct the Pantheon, the Coliseum, and ancient shipping ports throughout the Mediterranean.

"This implies the existence of a natural process in the subsurface of Campi Flegrei that is similar to the one that is used to produce concrete," said Tiziana Vanorio, an experimental geophysicist at Stanford's School of Earth, Energy & Environmental Sciences.

Campi Flegrei lies at the center of a large depression, or caldera, that is pockmarked by craters formed during past eruptions, the last of which occurred nearly 500 years ago. Nestled within this caldera is the colorful port city of Pozzuoli, which was founded in 600 B.C. by the Greeks and called "Puteoli" by the Romans.

Beginning in 1982, the ground beneath Pozzuoli began rising at an alarming rate. Within a two-year span, the uplift exceeded six feet-an amount unprecedented anywhere in the world. "The rising sea bottom rendered the Bay of Pozzuoli too shallow for large craft," Vanorio said.

Making matters worse, the ground swelling was accompanied by swarms of micro-earthquakes. Many of the tremors were too small to be felt, but when a magnitude 4 quake juddered Pozzuoli, officials evacuated the city's historic downtown. Pozzuoli became a ghost town overnight.

A teenager at the time, Vanorio was among the approximately 40,000 residents forced to flee Pozzuoli and settle in towns scattered between Naples and Rome. The event made an impression on the young Vanorio, and inspired her interests in the geosciences. Now an assistant professor at Stanford, Vanorio decided to apply her knowledge about how rocks in the deep Earth respond to mechanical and chemical changes to investigate how the ground beneath Pozzuoli was able to withstand so much warping before cracking and setting off micro-earthquakes.

"Ground swelling occurs at other calderas such as Yellowstone or Long Valley in the United States, but never to this degree, and it usually requires far less uplift to trigger earthquakes at other places," Vanorio said. "At Campi Flegrei, the micro-earthquakes were delayed by months despite really large ground deformations."

To understand why the surface of the caldera was able to accommodate incredible strain without suddenly cracking, Vanorio and a post-doctoral associate, Waruntorn Kanitpanyacharoen, studied rock cores from the region. In the early 1980s, a deep drilling program probed the active geothermal system of Campi Flegrei to a depth of about 2 miles. When the pair analyzed the rock samples, they discovered that Campi Flegrei's caprock-a hard rock layer located near the caldera's surface-is rich in pozzolana, or volcanic ash from the region.

The scientists also noticed that the caprock contained tobermorite and ettringite-fibrous minerals that are also found in humanmade concrete. These minerals would have made Campi Flegrei's caprock more ductile, and their presence explains why the ground beneath Pozzuoli was able to withstand significant bending before breaking and shearing. But how did tobermorite and ettringite come to form in the caprock?

Once again, the drill cores provided the crucial clue. The samples showed that the deep basement of the caldera-the "wall" of the bowl-like depression-consisted of carbonate-bearing rocks similar to limestone, and that interspersed within the carbonate rocks was a needle-shaped mineral called actinolite.

"The actinolite was the key to understanding all of the other chemical reactions that had to take place to form the natural cement at Campi Flegrei," said Kanitpanyacharoen, who is now at Chulalongkorn University in Thailand.

From the actinolite and graphite, the scientists deduced that a chemical reaction called decarbonation was occurring beneath Campi Flegrei. They believe that the combination of heat and circulating mineral-rich waters decarbonates the deep basement, prompting the formation of actinolite as well as carbon dioxide gas. 

As the CO2 mixes with calcium-carbonate and hydrogen in the basement rocks, it triggers a chemical cascade that produces several compounds, one of which is calcium hydroxide. Calcium hydroxide, also known as portlandite or hydrated lime, is one of the two key ingredients in humanmade concrete, including Roman concrete. Circulating geothermal fluids transport this naturally occurring lime up to shallower depths, where it combines with the pozzolana ash in the caprock to form an impenetrable, concrete-like rock capable of withstanding very strong forces.

"This is the same chemical reaction that the ancient Romans unwittingly exploited to create their famous concrete, but in Campi Flegrei it happens naturally," Vanorio said.

In fact, Vanorio suspects that the inspiration for Roman concrete came from observing interactions between the volcanic ash at Pozzuoli and seawater in the region. The Roman philosopher Seneca, for example, noted that the "dust at Puteoli becomes stone if it touches water."

"The Romans were keen observers of the natural world and fine empiricists," Vanorio said. "Seneca, and before him Vitruvius, understood that there was something special about the ash at Pozzuoli, and the Romans used the pozzolana to create their own concrete, albeit with a different source of lime."

Pozzuoli was the main commercial and military port for the Roman Empire, and it was common for ships to use pozzolana as ballast while trading grain from the eastern Mediterranean. As a result of this practice, volcanic ash from Campi Flegrei-and the use of Roman concrete-spread across the ancient world. Archeologists have recently found that piers in Alexandria, Caesarea, and Cyprus are all made from Roman concrete and have pozzolana as a primary ingredient.

Interestingly, the same chemical reaction that is responsible for the unique properties of the Campi Flegrei's caprock can also trigger its downfall. If too much decarbonation occurs-as might happen if a large amount of saltwater, or brine, gets injected into the system-an excess of carbon dioxide, methane and steam is produced. As these gases rise toward the surface, they bump up against the natural cement layer, warping the caprock. This is what lifted Pozzuoli in the 1980s. When strain from the pressure buildup exceeded the strength of the caprock, the rock sheared and cracked, setting off swarms of micro-earthquakes. As pent-up gases and fluids vent into the atmosphere, the ground swelling subsided. Vanorio and Kanitpanyacharoen suspect that as more calcium hydroxide was produced at depth and transported to the surface, the damaged caprock was slowly repaired, its cracks "healed" as more natural cement was produced.

Vanorio believes the conditions and processes responsible for the exceptional rock properties at Campi Flegrei could be present at other calderas around the world. A better understanding of the conditions and processes that formed Campi Flegrei's caprock could also allow scientists to recreate it in the lab, and perhaps even improve upon it to engineer more durable and resilient concretes that are better able to withstand large stresses and shaking, or to heal themselves after damage.

"There is a need for eco-friendly materials and concretes that can accommodate stresses more easily," Vanorio said. "For example, extracting natural gas by hydraulic fracturing can cause rapid stress changes that cause concrete well casings to fail and lead to gas leaks and water contamination."

For more information visit:-

http://www.sciencedaily.com/releases/2015/07/150709144850.htm

http://www.prlabs.co.uk/lab-supplies.php?N=graphite-powder&Id=58317

Pyroclastic flows

Pyroclastic flows are high-density mixtures of hot, dry rock fragments and hot gases that move away from the vent that erupted them at high speeds. They may result from the explosive eruption of molten or solid rock fragments, or both. They may also result from the nonexplosive eruption of lava when parts of dome or a thick lava flow collapses down a steep slope. Most pyroclastic flows consist of two parts: a basal flow of coarse fragments that moves along the ground, and a turbulent cloud of ash that rises above the basal flow. Ash may fall from this cloud over a wide area downwind from the pyroclastic flow.

Pyroclastic flows can reach speeds moving away from a volcano of up to 700 km/h (450 mph).  The gas can reach temperatures of about 1,000 °C (1,830 °F). Pyroclastic flows normally hug the ground and travel downhill, or spread laterally under gravity. Their speed depends upon the density of the current, the volcanic output rate, and the gradient of the slope. They are a common and devastating result of certain explosive volcanic eruptions.

A pyroclastic flow will destroy nearly everything in its path. With rock fragments ranging in size from ash to boulders traveling across the ground at speeds typically greater than 80 km per hour, pyroclastic flows knock down, shatter, bury or carry away nearly all objects and structures in their way. The extreme temperatures of rocks and gas inside pyroclastic flows can cause combustible material to burn, especially petroleum products, wood, vegetation, and houses.

Testimonial evidence from the 1883 eruption of Krakatoa, supported by experimental evidence, shows that pyroclastic flows can cross significant bodies of water. One flow reached the Sumatran coast as much as 48 km away.

Pyroclastic flows sweep down the flanks of Mayon Volcano, Philippines, in 1984

The towns of Pompeii and Herculaneum, Italy, for example, were engulfed by pyroclastic surges in 79 AD with many lives lost.

"Garden of the Fugitives". Plaster casts of victims still in situ; many casts are in the Archaeological Museum of Naples.

For more information and some video clips visit:-
http://www.geo.mtu.edu/volcanoes/hazards/primer/pyro.html
http://en.wikipedia.org/wiki/Pyroclastic_flow
http://volcanoes.usgs.gov/hazards/pyroclasticflow/