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Showing posts with label bronze. Show all posts
Showing posts with label bronze. Show all posts

Monday, 27 February 2017

The chemistry behind the 'Oscar'

A BIT of a mix up might have dinted the magical chemistry of the Oscars this year, but it didn’t damage the sheen on those golden statuettes! 

So, what exactly IS the chemistry behind the world’s most famous prize? Check out the graphic below to learn exactly WHAT goes into an Oscar statuette. 

Source: Compound Interest


So, who knew the statuette wasn’t made from REAL gold? And what is the history of Britannium? First produced in 1769 or 1770, Britannium metal was created by James Vickers after purchasing the formula from a dying friend. It was originally known as "Vickers White Metal" when made under contract by the Sheffield manufacturers Ebenezer Hancock and Richard Jessop. In 1776 James Vickers took over the manufacturing himself and remained as owner until his death in 1809, when the company passed to his son, John, and Son-in-Law, Elijah West. In 1836 the company was sold to John Vickers's nephew Ebenezer Stacey (the son of Hannah Vickers and John Stacey).

After the development of electroplating with silver in 1846, Britannia metal was widely used as the base metal for silver-plated household goods and cutlery. The abbreviation EPBM on such items denotes "electroplated Britannia metal". Britannia metal was generally used as a cheaper alternative to electroplated nickel silver (EPNS) which is more durable.

In his essay, A Nice Cup of Tea, writer George Orwell asserts that "britanniaware" teapots "produce inferior tea" (when compared to Chinaware).

For more information visit:-

http://www.compoundchem.com/2017/02/25/oscars/
http://www.prlabs.co.uk/lab-supplies.php?N=copper-1000ppm-for-icp&Id=60111
https://en.wikipedia.org/wiki/Britannia_metal



Tuesday, 16 August 2016

What are Olympic medals made of?

So, the Olympic medals are made of gold, silver and bronze right? Wrong! Pure gold medals would cost an awful lot, so what are the medals really made from? 

The graphic below looks at the different metals used.

Graphic: Compound Interest

So, what of real gold? Let’s find out more:

Gold is a chemical element with the symbol Au (from Latin: aurum) and the atomic number 79. In its purest form, it is a bright, slightly reddish yellow, dense, soft, malleable and ductile metal. Chemically, gold is a transition metal and a group 11 element. It is one of the least reactive chemical elements, and is solid under standard conditions. The metal therefore occurs often in free elemental (native) form, as nuggets or grains, in rocks, in veins and in alluvial deposits. It occurs in a solid solution series with the native element silver (as electrum) and also naturally alloyed with copper and palladium. Less commonly, it occurs in minerals as gold compounds, often with tellurium (gold tellurides).

Gold's atomic number of 79 makes it one of the higher atomic number elements that occur naturally in the universe. It is thought to have been produced in supernova nucleosynthesis and from the collision of neutron stars and to have been present in the dust from which the Solar System formed. Because the Earth was molten when it was just formed, almost all of the gold present in the early Earth probably sank into the planetary core. Therefore, most of the gold that is present today in the Earth's crust and mantle is thought to have been delivered to Earth later, by asteroid impacts during the Late Heavy Bombardment, about 4 billion years ago.

Gold resists attack by individual acids, but aqua regia (literally "royal water", a mixture of nitric acid and hydrochloric acid) can dissolve it. The acid mixture causes the formation of a soluble tetrachloroaurate anion. It is insoluble in nitric acid, which dissolves silver and base metals, a property that has long been used to refine gold and to confirm the presence of gold in metallic objects, giving rise to the term acid test. Gold also dissolves in alkaline solutions of cyanide, which are used in mining and electroplating. Gold dissolves in mercury, forming amalgam alloys, but this is not a chemical reaction.

Gold is a precious metal used for coinage, jewellery, and other arts throughout recorded history. In the past, a gold standard was often implemented as a monetary policy within and between nations, but gold coins ceased to be minted as a circulating currency in the 1930s, and the world gold standard was abandoned for a fiat currency system after 1976. The historical value of gold was rooted in its relative rarity, easy handling and minting, easy smelting and fabrication, resistance to corrosion and other chemical reactions (nobility), and distinctive colour.

The world consumption of new gold produced is about 50% in jewellery, 40% in investments, and 10% in industry. Gold's high malleability, ductility, resistance to corrosion and most other chemical reactions, and conductivity of electricity have led to its continued use in corrosion resistant electrical connectors in all types of computerized devices (its chief industrial use). Gold is also used in infrared shielding, coloured glass production, gold leafing, and tooth restoration. Certain gold salts are still used as anti-inflammatories in medicine.

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Monday, 13 June 2016

Dagger in Tutankhamun's tomb was made with iron from a meteorite

A dagger entombed with King Tutankhamun was made with iron from a meteorite, a new analysis on the metal composition shows.

In 1925, archaeologist Howard Carter found two daggers, one iron and one with a blade of gold, within the wrapping of the teenage king, who was mummified more than 3,300 years ago. The iron blade, which had a gold handle, rock crystal pommel and lily and jackal-decorated sheath, has puzzled researchers in the decades since Carter’s discovery: ironwork was rare in ancient Egypt, and the dagger’s metal had not rusted.

Italian and Egyptian researchers analysed the metal with an x-ray fluorescence spectrometer to determine its chemical composition, and found its high nickel content, along with its levels of cobalt, “strongly suggests an extraterrestrial origin”. They compared the composition with known meteorites within 2,000km around the Red Sea coast of Egypt, and found similar levels in one meteorite.

That meteorite, named Kharga, was found 150 miles (240km) west of Alexandria, at the seaport city of Mersa Matruh, which in the age of Alexander the Great – the fourth century BC – was known as Amunia.

The researchers published their findings on Tuesday in the journal Meteoritics & Planetary Science.

Although people have worked with copper, bronze and gold since 4,000BC, ironwork came much later, and was rare in ancient Egypt. In 2013, nine blackened iron beads, excavated from a cemetery near the Nile in northern Egypt, were found to have been beaten out of meteorite fragments, and also a nickel-iron alloy. The beads are far older than the young pharaoh, dating to 3,200BC.

“As the only two valuable iron artifacts from ancient Egypt so far accurately analysed are of meteoritic origin,” the team that studied the knife wrote, “we suggest that ancient Egyptians attributed great value to meteoritic iron for the production of fine ornamental or ceremonial objects”.

The researchers also stood with a hypothesis that ancient Egyptians placed great importance on rocks falling from the sky. They suggested that the finding of a meteorite-made dagger adds meaning to the use of the term “iron” in ancient texts, and noted around the 13th century BC, a term “literally translated as ‘iron of the sky’ came into use … to describe all types of iron”.

“Finally, somebody has managed to confirm what we always reasonably assumed,” Thilo Rehren, an archaeologist with University College London, told the Guardian.

Rehren, who studied the nine meteoritic beads, said “there never has been a reason to doubt this outcome but we were never really able to put this hard data behind it”.

He added that other objects from Tutankhamun’s tomb, including jewelry and miniature daggers, are believed to made from meteorite iron.

“Yes, the Egyptians referred to this stuff as metal from the heaven, which is purely descriptive,” he said. “What I find impressive is that they were capable of creating such delicate and well manufactured objects in a metal of which they didn’t have much experience.”

An iron meteorite, by James St. John (Flickr: Murnpeowie Meteorite) [CC BY 2.0 (http://creativecommons.org/licenses/by/2.0)], via Wikimedia Commons
The researchers wrote in the new study: “The introduction of the new composite term suggests that the ancient Egyptians were aware that these rare chunks of iron fell from the sky already in the 13th [century] BCE, anticipating Western culture by more than two millennia.”

Egyptologist Joyce Tyldesley, of the University of Manchester, has similarly argued that ancient Egyptians would have revered celestial objects that had plunged to earth.

“The sky was very important to the ancient Egyptians,” she told Nature, apropos of her work on the meteoritic beads. “Something that falls from the sky is going to be considered as a gift from the gods.”

The high quality of the blade suggests that Tutankhamun, who lived during the latest stage of the Bronze Age, was supported by ironworkers who were skilled despite the relative rarity of the material.

The blade may not be the only item derived from falling rocks on Tut’s person.

In 2006, an Austrian astrochemist proposed that an unusual yellowish gem, shaped as a scarab in King Tut’s burial necklace, is actually glass formed in the heat of a meteorite crashing into sand.

“It would be very interesting to analyse more pre-Iron Age artifacts, such as other iron objects found in King Tut’s tomb,” Daniela Comelli, of the physics department at Milan Polytechnic, told Discovery News. “We could gain precious insights into metal working technologies in ancient Egypt and the Mediterranean.”

For more information visit:-